(A) In Agriculture and Food:
- For optimal plant growth, Chemistry has introduced various types of chemical fertilizers such as urea, calcium phosphate, sodium nitrate, ammonium phosphate, etc.
- This has helped us protect our products from harmful insects and bacteria by using effective insecticides, fungicides and insecticides.
- The use of preservatives has helped us to extend the shelf life of foods and beverages such as jam, butter, squash, etc.
- It has provided mankind with a variety of life-saving drugs.
- Today, dysentery and pneumonia can be cured thanks to the discovery of life-saving sulfa drugs and penicillin drugs.
- Cisplatin and Taxol have been shown to be highly effective in treating cancer and AZT (azidothymidine) is used for AIDS victims.
- Disinfectants such as phenol are used to kill microorganisms found in drains, toilets, floors, etc.
- Low concentration of chlorine, i.e. 0.2 to 0.4 parts per million (ppm), used to sterilize water to make it suitable for drinking.
- Rapid industrialization around the world has caused a lot of pollution.
- Toxic gases such as CFCs and chemicals are constantly released into the atmosphere.
- They are polluting the environment at an alarming rate.
- Scientists are working day and night to develop alternatives that can reduce pollution.
- For example, methane (compressed natural gas), an alternative to gasoline, is very effective in screening for car pollution.
- Chemistry has played an important role in the development of many consumer goods produced in industry.
- Commodities such as fertilizers, alkalis, acids, salts, dyes, polymers, drugs, soaps, detergents, metal alloys and other inorganic and organic chemicals, including new materials, make a major contribution to strengthening the national economy.
• Matter
Matter is anything which has mass and hence occupies space.
For example, A book, a pen, soil, water, air are composed of matter.
These these substances have mass and also they occupy space.
• Classification of Matter
There are two ways of classifying the matter:
(A) Physical classification
(B) Chemical classification
(A) Physical Classification:
1. Solids: The particles of solid are held very close to each other in an orderly fashion and there is not much freedom of movement for the particles.
Characteristics of solids: Solids have definite volume and definite shape.
2. Liquids: In liquids, the particles are so close to each other and still they are able to slide over one another. Their ability to flow gives them a name, Fluid.
Characteristics of liquids: Liquids have definite volume but no definite shape, as they adapt to the shape of the container they are put inside.
3. Gases: In gases, the particles are far apart as compared to those present in solid or liquid states. Their movement is easy, random and fast.
Characteristics of Gases: Gases have neither definite volume nor definite shape. They completely occupy the container in which they are placed.
(B) Chemical Classification:
Based upon the composition, matter can be divided into two main types:
1. Pure Substances
2. Mixtures.
1. Pure substances:
A pure substance may be defined as a single substance (or matter) which cannot be separated by simple physical methods.
Pure substances can be further classified as (i) Elements (ii) Compounds
(i) Elements:
- An element consists of only one type of particles. These particles may be atoms or molecules.
- For example, Sodium, Copper, Silver, Hydrogen, Oxygen etc. are some examples of elements.
- They all contain atoms of the same type.
- However, atoms of different elements are different in nature.
- Some elements such as Sodium or Copper contain single atoms held together as their constituent particles whereas in some others two or more atoms combine to give molecules of the element.
- As in Sulphur(S₈ ) and Phosphorous(P₄ ) there are 8 and 4 atoms respectively to form a Homoatomic molecule.
- Thus, Hydrogen( H₂ ), Nitrogen( N₂ ) and Oxygen( O₂ ) gases consist of Homoatomic molecules in which two atoms combine to give the respective molecules of the element.
- The Elements have been classified into three types. These are:
- Metals
- Metalloids
- Nonmetals
- Metals :
Metals are substances characterized by high electrical and thermal conductivity as well as by malleability, ductility, rigidity and high reflectivity of light.
- Approximately three-quarters of all known chemical elements are metals.
- The most abundant varieties in the Earth’s crust are aluminum, iron, calcium, sodium, potassium, and magnesium.
- The vast majority of metals are found in ores (mineral-bearing substances), but a few such as copper, gold, platinum, and silver frequently occur in the free state because they do not readily react with other elements.
- Semi Metals or Metalloids:
- Non metals:
- Like metals, Nonmetals may occur in the solid, liquid, or gaseous state.
- However, unlike metals, nonmetals display a wide range of both mechanical and optical properties, ranging from brittleness to plasticity and from transparency to opaqueness.
From the chemical point of view, nonmetals may be divided into two classes:
1) Covalent substances:
Covalent substances contain atoms having small sizes, high electronegativities, low valence vacancy to electron ratios.
These atoms exhibit a pronounced tendency to form negative ions in chemical reactions and negative oxidation states in their compounds;
2) Ionic substances:
Ionic substances contain both small and large atoms.
- Ions may be formed by adding electrons to (small, electronegative atoms) or by extracting electrons from (large, electropositive) atoms.
- Ions in Ionic substances are bound to each other by strong electrostatic forces of attraction.
The compounds have been classified into two types. These are:
- These are compounds which are obtained from non-living sources such as rocks and minerals.
- A few examples are: Common salt, marble, gypsum, washing soda etc.
2. Mixtures:
Types of mixtures: Mixtures are of two types:
(i) Homogeneous mixtures:
(ii) Heterogeneous mixtures:
For example:
• Differences between Compounds and Mixtures
Compounds
1. In a compound, two or more elements are combined chemically.
2. In a compound, the elements are present in the fixed ratio by mass. This ratio cannot change.
3. Compounds are always homogeneous i.e., they have the same composition throughout.
4 In a compound, constituent particles cannot be separated by physical methods.
5. In a compound, the constituent particles lose their identities i.e., a compound does not show the characteristics of the constituting elements.
Mixtures
1. In a mixture, or more elements or compounds are simply mixed and not combined chemically.
2. In a mixture the constituent particles are not present in fixed ratio. The ratio can vary.
3. Mixtures may be either homogeneous or heterogeneous in nature.
4. Constituent particles of mixtures can be separated by physical methods.
5, In a mixture, the constituent particles do not lose their identities, i.e., a mixture shows the characteristics of all the constituents .
We have discussed the physical and chemical classification of matter. A flow chart representation of the same is given below.
Physical Properties: These are the properties which can be measured or observed without changing the identity or the composition of the substance.
• Units of Measurement
Fundamental Units:
There are seven basic units of measurement for the quantities: length, mass, time, electric current, temperature, , luminous intensity and amount of substance.
S.I. System: This system of measurement is the most common system employed throughout the world.
It has given units of all the seven basic quantities listed above.
1. Metre:
2. Kilogram:
3. Second:
4. Kelvin:
5. Ampere:
6. Candela:
7. Mole: It is the amount of substance which contains as many
• Mass and Weight
Mass:
The mass of a substance can be determined accurately in the
It has the units of (length)³.
In SI units, volume is expressed in metre³ (m³).
However, a popular unit of measuring volume, is litre (L).
But it is not an SI unit .
Mathematically,
1L = 1000 mL = 1000 cm³ = 1dm³.
Volume of liquids can be measured by different devices
like Burette, Pipette, Cylinder, Measuring flask etc.
Temperature: There are three scales in which temperature can be measured. These are known as Celsius scale (°C), Fahrenheit scale (°F) and Kelvin scale (K).
- Thermometers with Celsius scale are calibrated from 0°C to 100°C.
- Thermometers with Fahrenheit scale are calibrated from 32°F to 212°F.
- Kelvin scale of temperature is S.I. scale and is very common these days. Temperature on this scale is shown by the sign K.
- The temperature on two scales are related to each other by the relationship :
Idea of the ranges of temperature :
• Uncertainty in Measurements
All scientific measurements involve certain degree of error or uncertainty. The errors which arise depend upon two factors.
(i) Skill and accuracy of the worker (ii) Limitations of measuring instruments.
• Scientific Notation
It is an exponential notation in which any number can be represented in the form N x 10n where n is an exponent having positive or negative values and N can vary between 1 to 10. Thus, 232.508 can be written as 2.32508 x 102 in scientific notation.
Now let us see how calculations are carried out with numbers expressed in scientific notation.
(i) Calculation involving multiplication and division
(ii) Calculation involving addition and subtraction: For these two operations, the first numbers are written in such a way that they have the same exponent. After that, the coefficients are added or subtracted as the case may be. For example,
• Significant Figures
Significant figures are meaningful digits which are known with certainty. There are certain rules for determining the number of significant figures. These are stated below:
1. All non-zero digits are significant. For example, in 285 cm, there are three significant figures and in 0.25 mL, there are two significant figures.
2. Zeros preceding to first non-zero digit are not significant. Such zeros indicates the position of decimal point.
For example, 0.03 has one significant figure and 0.0052 has two significant figures.
3. Zeros between two non-zero digits are significant. Thus, 2.005 has four significant figures.
4. Zeros at the end or right of a number are significant provided they are on the right side of the decimal point. For example, 0.200 g has three significant figures.
5. Counting numbers of objects. For example, 2 balls or 20 eggs have infinite significant figures as these are exact numbers and can be represented by writing infinite number of zeros after placing a decimal.
i.e., 2 = 2.000000
or 20 = 20.000000
• Addition and Subtraction of Significant Figures
In addition or subtraction of the numbers having different precisions, the final result should be reported to the same number of decimal places as in the term having the least number of decimal places.
For example, If we carry out the addition of three numbers 3.52, 2.3 and 6.24, having different precisions or different number of decimal places.
In the multiplication or division, the final result should be reported up to the same number of significant figures as present in the least precise number.
Multiplication of Numbers:
According to the rule the final result = 0.024
Division of Numbers:
According to the rule the final result = 1.12
• Dimensional Analysis
Often while calculating, there is a need to convert units from one system to other. The method used to accomplish this is called factor label method or unit factor method or dimensional analysis.
• Laws of Chemical Combinations
(i) Law of Conservation of Mass
(ii) Law of Definite Proportions
(iii) Law of Multiple Proportions
(iv) Law of Gaseous Volume (Gay Lussac’s Law)
(v) Avogadro’s Law
(i) Law of Conservation of Mass
The law was established by a French chemist, A. Lavoisier. The law states:
In all physical and chemical changes, the total mass of the reactants is equal to that of the products.
In other words, matter can neither be created nor destroyed.
The following experiments illustrate the truth of this law.
(a) When matter undergoes a physical change.
(ii) Law of Definite Proportions :
According to this law:
A pure chemical compound always consists of the same elements combined together in a fixed proportion by weight.
For example, Carbon dioxide may be formed in a number of ways i.e.,
For example,
The law states that,
(a) Combination between Hydrogen and Chlorine:
(b) Combination between Nitrogen and Hydrogen: The two gases lead to the formation of ammonia gas under suitable conditions. The chemical equation is
During the reaction of hydrogen and oxygen to produce water, we see that two volumes of hydrogen combine with one volume of oxygen to give two volumes of water without leaving any unreacted oxygen. The ratio of the volumes in this case is found to be a simple whole number ratio.
- Indivisibility of atoms : Matter consists of indivisible atoms.
- Identical properties : All the atoms of a given element have identical properties including identical mass.
- Uniqueness of Atoms : Atoms of different elements differ in mass.
- Definite proportions : Compounds are formed when atoms of different elements combine in a fixed ratio.
- Conservation of matter : Chemical reactions involve reorganization of atoms. In a chemical reaction, these are neither created nor destroyed .
• Atomic Mass
The atomic mass of an element is the number of times an atom of that element is heavier than an atom of carbon taken as 12. It may be noted that the atomic masses as stated above are the relative atomic masses and not the actual masses of the atoms.
One atomic mass unit (a m u) is equal to l/12th of the mass of an atom of carbon-12 isotope. It is also known as unified mass.
Average Atomic Mass
Most of the elements exist as isotopes which are different atoms of the same element with different mass numbers and the same atomic number. Therefore, the atomic mass of an element must be its average atomic mass.
Molecular Mass
Molecular mass is the sum of atomic masses of the elements present in a molecule. It is obtained by multiplying the atomic mass of each element by number of its atoms and adding them together.
For example,
Molecular mass of methane (CH₄)
= 12.011 u + 4 (1.008 u)
= 16.043 u
The mass of a substance especially in grams that combines with or is chemically equivalent to 1.8 grams of Hydrogen, 8 grams of oxygen or 35.5 grams of Chlorine , the atomic or molecular weight divided by the valency of an element also gives the Equivalent Mass.
Formula Mass
Ionic compounds such as NaCl, KNO3, Na2C03 etc. do not consist of molecules i.e., single entities but exist “as ions are closely packed together in a three dimensional space as shown in -Fig. 1.5.
= 23.0 u + 35.5 u = 58.5 u.
• Mole Concept :
- One gram atom of any element is found to contain the same number of atoms and one gram molecule of any substance contains the same number of molecules.
- This number has been experimentally found to be equal to 6.022137 x 1023 .
- It is generally called Avogadro’s number or Avogadro’s constant.
- It is usually represented by N🇦 .
- Avogadro’s Number, N🇦 = 6.022 × 1023
- One mole of a substance at NTP weighs equal to the Molecular Mass of the substance.
- One mole of a substance at NTP occupies a volume equal to the Gram Molecular Volume (22.4 L ) of the substance.
- One mole of a substance at NTP weighs equal to the molar mass of the substance.
- One mole of molecules of a substance at NTP weighs equal to the Molecular mass of the substance.(One gram molecule or GMM)
- One mole of atoms of a substance at NTP weighs equal to the Atomic mass of the substance. (One gram atom or GAM)
- One mole of a substance at NTP contains Avogadro number of particles.
One can check the purity of a given sample by analyzing this data.
The formula of the compound which gives the simplest whole number ratio of the atoms of various elements present in one molecule of the compound.
For example, the formula of Hydrogen peroxide is H202.
Common factor = 6
The ratio is = 1 : 2 : 1 The empirical formula of glucose = CH20
• Molecular Formula
The formula of a compound which gives the actual ratio of the atoms of various elements present in one molecule of the compound.
For example,
Molecular formula = n x Empirical formula
Where n is the common factor and also called multiplying factor. The value of n may be 1, 2, 3, 4, 5, 6 etc.
If case n= 1, then
• Stoichiometry and Stoichiometric Calculations
The word ‘stoichiometry’ is derived from two Greek words—Stoicheon (meaning element) and metron (meaning measure). Stoichiometry, thus deals with the calculation of masses (sometimes volume also) of the reactants and the products involved in a chemical reaction.
Sometimes, in alchemical equation, the reactants present are not the amount as required according to the balanced equation. The amount of products formed then depends upon the reactant which has reacted completely. This reactant which reacts completely in the reaction is called the limiting reactant or limiting reagent. The reactant which is not consumed completely in the reaction is called excess reactant.
Reactions in Solutions
When the reactions are carried out in solutions, the amount of substance present in its given volume can be expressed in any of the following ways:
1. Mass percent or weight percent (w/w%)
2. Mole fraction
3. Molarity
4. Molality
1. Mass percent: It is obtained by using the following relation:
4. Molality: It is defined as the number of moles of solute present in 1 kg of solvent. It is denoted by m.
• All substances contain matter which can exist in three states — solid, liquid or gas.
• Matter can also be classified into elements, compounds and mixtures.
• Element: An element contains particles of only one type which may be atoms or molecules.
• Compounds: Compounds are formed when atoms of two or more elements combine in a fixed ratio to each other.
• Mixtures: Mixtures are the substances present around us which contain two or more pure substances in different ratios, combined physically or chemically.
• Scientific notation: The measurement of quantities in chemistry are spread over a wide range of 10-31to 1023. Hence, a convenient system of expressing the number in scientific notation is used.
• Scientific figures: The uncertainty is taken care of by specifying the number of significant figures in which the observations are reported.
• Dimensional analysis: It helps to express the measured quantities in different systems of units.
• Laws of Chemical Combinations are:
(i) Law of Conservation of Mass
(ii) Law of Definite Proportions
(iii) Law of Multiple Proportions
(iv) Gay Lussac’s Law of Gaseous Volumes
(v) Avogadro’s Law.
• Atomic mass: The atomic mass of an element is expressed relative to 12C isotope of carbon which has an exact value of 12u.
• Average atomic mass: Obtained by taking into account the natural abundance of different isotopes of that element.
• Molecular mass: The molecular mass of a molecule is obtained by taking sum of atomic masses of different atoms present in a molecule.
• Avogadro number: The number of atoms, molecules or any other particles present in a given system are expressed in terms of Avogadro constant.
= 6.022 x 1023
• Balanced chemical equation: A balanced equation has the same number of atoms of each element on both sides of the equation.
• Stoichiometry: The quantitative study of the reactants required or the products formed is called stoichiometry. Using stoichiometric calculations, the amounts of one or more reactants required to produce a particular amount of product can be determined and vice-versa.
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